• A deeper insight into direct trifluoromethoxylation with trifluoromethyl triflate. Olivier Marrec, Thierry Billard, Jean-Pierre Vors, Sergii Pazenok, Bernard R. Langlois. J. Fluorine Chem. 2010, 131, 200-207.

  • Trifluoromethanesulfanylamides as Easy-to-Handle Equivalents of the Trifluoromethanesulfanyl Cation (CF3S+): Reaction with Alkenes and Alkynes. Aurélien Ferry, Thierry Billard, Bernard R. Langlois, and Eric Bacqué. Angew. Chem. Int. Ed. 2009, 48, 8551-8555.

  • A simple access to metallic or onium bistrifluoromethanesulfonimide salts. Arvai, R.; Toulgoat, F.; Langlois, B. R.; Sanchez, J-.Y.; Médebielle, M. Tetrahedron 2009, 65, 5361-5368.

  • 2,2'-Bipyridine-3,3'-dicarboxylic carbohydrate esters and amides. Synthesis and preliminary evaluation as ligands in Cu(II) catalysed enantioselective electrophilic fluorination. Assalit, A. ; Billard, T. ; Chambert, S. ; Langlois, B.R. ; Queneau, Y. ; Coe, D. Tetrahedron Asymmetry 2009, 20, 593-601.

  • Effects of amyloid-beta peptides on the serotoninergic 5-HT(1A) receptors in the rat hippocampus. Verdurand, M ; Bérod, A ; Le Bars, D ; Zimmer, L. Neurobiol Aging. 2009 sous presse

  • Association between triallelic polymorphism of the serotonin transporter and [(18)F]MPPF binding potential at 5-HT(1A) receptors in healthy subjects. Lothe, A; Boni, C; Costes, N ; Gorwood, P ; Bouvard, S ; Le Bars, D ; Lavenne, F ; Ryvlin, P. NeuroImage 2009, 47, 482-492.

  • Copper-Catalyzed Aerobic Oxidative Rearrangement of Tertiary Allylic Alcohols Mediated by TEMPO. Vatèle, J.-M. Synlett 2009, 2143-2145.

  • A simple access to metallic or onium trifluoromethanesulfonimide salts. Arvai, R ; Toulgoat, F.; Langlois, B.R. ; Sanchez, J.Y.; Medebielle, M. Tetrahedron 2009, 67, 5361-5368.

  • Synthesis of β-Trifluoromethylated Enones: AnUnexpected Reactivity of Trifluoromethylated Weinreb Enamides towards Organolithium Species. Marrec, O.; Borrini, J.; Billard, T.; Langlois, B.R. Synlett 2009, 1241-1244.

  • Synthesis, characterization and catalytic properties of a highly stereoselective olefin metathesis catalyst. Rhers, B.; Grinenval, E.; Taoufik, M.; Fache, F.; Herdtweck, E.; Basset, J-M.; Lefebvre, F. Catalysis Communications 2009, 10, 1111–1116.

  • Access to the core structure of the macrolactone aurisides by a RCM / transannular ketalisation sequence. Bourcet, E.; Fache, F.; Piva, O. Tetrahedron Letters 2009, 50, 1787-1790.

  • A Short access to 3-hydroxy-4-hydroxymethyltetrahydrofurans: Application to the total synthesis of amphiasterin B4. Salim, H.; Piva, O. J. Org. Chem. 2009, 74, 2257-2260.

  • Efficient preparation of new fluorinated lithium and ammonium sulfonimides. Toulgoat, F.; Langlois, B.; Médebielle, M.; Sanchez, J-.Y. J. Org. Chem. 2008, 73, 5613-5616.

  • New aryl-containing fluorinated sulfonic acids and their ammonium salts, useful as electrolytes for fuel cells or ionic liquids. Arvai, R.; Toulgoat, F.; Médebielle, M.; Langlois, B.; Alloin, F.; Iojou, C.; Sanchez, J-.Y. J. Fluorine Chem. 2008, 129, 1029-1035.

  • 2,6-Disubstituted tetrahydropyrans by tandem cross-metathesis / iodocyclisation. Hiebel, M.A.; Pelotier, B.; Goekjian, P.; Piva, O. Eur. J. Org. Chem. 2008, 713-720.

  • Synthesis of Bistramide A and analogues - Part.1: Stereoselective access to nor-methyl tetrahydropyran subunit. Hiebel, M.A.; Pelotier, B.; Lhoste, P.; Piva, O. Synlett 2008, 1202-1204.

  • Organic Background of Restrictive-Type Anorexia Nervosa Suggested by Increased Serotonin(1A) Receptor Binding in Right Frontotemporal Cortex of Both Lean and Recovered Patients: [18F]MPPF PET Scan Study. Galusca, B ; Costes, N ; Zito, Ng ; Peyron, R ; Bossu, C ; Lang, F ; Le Bars, D ; Estour, B. Biol Psychiatry. 2008, 64, 1009-1013.

  • Automated radiosynthesis of the Pittsburg compound-B using a commercial synthesizer. Verdurand, M ; Bort, G ; Tadino, V ; Bonnefoi, F ; Le Bars, D ; Zimmer, L. Nucl Med Commun. 2008, 29, 920-926.

  • Globus pallidus stimulation reduces frontal hyperactivity in tardive dystonia. Thobois, S. ; Ballanger, B. ; Xie-Brustolin, J. ; Damier, P. ; Durif, F. ; Azulay, Jp ; Derost, P. ; Witjas, T. ; Raoul, S. ; Le Bars, D. ; Broussolle, E. J Cereb Blood Flow Metab. 2008, 28, 1127-1138.

  • Le fluor 18 en radiopharmacie. De Beco, V. ; Le Bars D. ; Scherrmann, J.-M. Annales Pharmaceutiques Françaises 2008

  • A distinct [18F]MPPF PET profile in amnestic mild cognitive impairment compared to mild Alzheimer's disease. Truchot, L. ; Costes, N. ; Zimmer, L. ; Laurent, B. ; Le Bars, D. ; Thomas-Antérion, C. ; Mercier, B. ; Hermier, M. ; Vighetto A. ; Krolak-Salmon, P. NeuroImage 2008, 40,1251-1256.

  • In vitro and in vivo studies with [18F]Fluorocholine on digestive tumoral cell lines and in an animal model of metastasized endocrine tumor. Nejjari, M. ; Kryza, D. ; Poncet, G. ; Roche, C. ; Perek, N. ; Chayvialle, Ja ; Le Bars, D. ; Scoazec, Jy ; Janier, M. ; Borson-Chazot, F. Nucl Med Biol 2008, 35, 123-130.

  • Synthesis of Trifluoromethanesulfinamidines and Sulfanylamides. Ferry, A. ; Billard, T. ; Langlois, B.R. ; Bacque, E. J. Org. Chem. 2008,73, 9362-9365.

  • Use of Cyclic α,β-Unsaturated Trifluoromethyl Sulfones in Diels-Alder Cycloadditions and Michael Additions. Billard, T. ; Langlois, B.R. ; Essers, M. ; Haufe, G. Czech. Coll. Chem. Commun. 2008, 73 (12), 1814-1824.

  • Preparation of New Fluorinated Sulfonates for Lithium Batteries and Fuel Cells. Arvai, R. ; Toulgoat, F. ; Medebielle, M. ; Langlois, B.R. ; Sanchez, J.Y. J. Fluorine Chem. 2008, 129, 1029-1035.

  • Efficient Preparation of New Fluorinated Lithium and Ammonium Sulfonimides. Toulgoat, F. ; Langlois, B.R. ; Medebielle, M. ; Sanchez, J.Y. J. Org. Chem. 2008, 73, 5613-5616.

  • Tandem cross-metathesis / hydrogenation: Application to an enantioselective synthesis of pentadecyl 6-hydroxypentadecanoate. Bourcet, E. ; Virolleaud, M.A.; Fache, F.; Piva, O. Tetrahedron Lett. 2008, 49, 6816-6818.

  • Rapid cleavage of unactivated, unstrained amide bonds at neutral pH. Fernandes, N. M.; Fache, F.; Rosen, M.; Nguyen, PL.; Hansen, D. E. J. Org. Chem. 2008, 73, 6413-6416.

  • One single catalyst, Pd(OAc)2 for two sequential very different steps: Allylic alcohol oxidation-Heck reaction. Access to functionalised α,β-unsaturated ketones. Batt, F.; Gozzi, C.; Fache, F. Chem. Commun. 2008, 5830-5832.

  • A short access to highly strained spiranic compounds from ethyl 3-cyclobutylprop-2-enoate. Salim, H.; Piva, O. Tetrahedron Lett. 2008, 49, 2994-2995.

  • Designer amphiphiles based on para-acyl-calix[8]arenes. Jebors, S.; Fache, F. ; Balme, S. ; Devoge, F.; Monachino, M.; Cecillon, S.; Coleman, A. W. Org. Biomol. Chem. 2008, 6, 319-329.

  • Unexpected tosyl deprotection during osmium catalyzed dihydroxylation. Batt, F.; Piva, O.; Fache, F. Tetrahedron Lett. 2008, 49, 566-568.

  • Synthesis and biological evaluation in rat and cat of [18F]12ST05 as a potential 5-HT6 PET radioligand. Tang, S.; Verdurand, M. ; Joseph, B. ; Lemoine, L. ; Daoust, A. ; Billard, T. ; Fournet, G. ; Le Bars, D. ; Zimmer, L. Nucl. Med. Biol. 2007, 34, 9995–10002.

  • Organic molecules of biological interest: new synthetic approaches using the tetrakis(dimethylamino)ethylene (TDAE). Médebielle, M.; Langlois, B.; Billard, T.; Vanelle, P.; Terme, T.; Dolbier, Jr, W. R.; Okada, E.; Kato, K. Act. Chim. Ther. 2007, 33, A1-A18.

  • Electrochemical investigation of polymer electrolytes based on lithium 2-(phenylsulfanyl)-1,1,2,2-tetrafluorotthanesulfonate. Paillard, E.; Toulgoat, F.; Sanchez, J-.Y.; Médebielle, M.; Iojoiu, C.; Alloin, F.; Langlois, B. Electrochimica Acta. 2007, 53, 1439-1443.

  • An efficient preparation of new sulfonyl fluorides and lithium sulfonates. Toulgoat, F.; Langlois, B.; Médebielle, M.; Sanchez, J-.Y. J. Org. Chem. 2007, 72, 9046-9052.

  • Total synthesis of (+/-)-diospongin via Prins reaction. Hiebel, M. A.; Pelotier, B.; Piva, O. Tetrahedron 2007, 63, 7874-7878.

  • Lewis-acid Promoted Rearrangement of Tertiary Allylic Alcohols with PhIO/TEMPO System. Vatèle, J.-M. Synlett 2008, 1785-1788.

  • MPPF et imagerie des récepteurs 5HT1A de la sérotonine. Le Bars, D. Médecine Nucléaire 2007, 31, 493-497.

  • Purification of [(18)F]-fluoro-l-thymidine ([(18)F]-FLT) for positron emission tomography imaging. Bourgeois, M. ; Mougin-Degraef, M. ; Leost, F. ; Cherel, M. ; Gestin, Jf ; Le Bars, D. ; Barbet, J. ; Faivre-Chauvet, A. J Pharm Biomed Anal 2007, 45, 154-157.

  • Functional anatomy of motor urgency Thobois, S. ; Ballanger, B. ; Baraduc, P. ; Le Bars, D. ; Lavenne, F. ; Broussolle, E. ; Desmurget, M. NeuroImage 2007, 37, 243-252.

  • Test-retest reproducibility of [18F]MPPF PET in Healthy Humans : a reliability study. Costes, N. ; Zimmer, L. ; Reilhac, A. ; Lavenne, F. ; Ryvlin, P. ; Le Bars, D. J. Nucl. Med. 2007, 48, 1279-1288.

  • Up-regulation of hippocampal serotonin metabolism in mild cognitive impairment. Truchot, L. ; Costes, N. ; Zimmer, L. ; Laurent, B. ; Le Bars, D. ; Thomas-Antérion, C. ; Croisile, B. ; Mercier, B. ; Hermier, M. ; Vighetto, A. ; Krolak-Salmon, P. Neurology 2007, 69, 1012-1017.

  • How to reach stereogenic trifluoromethylated carbons ? En route for the Graal of the asymmetric trifluoromethylation. Billard, T. ; Langlois, B. R. Eur. J. Org. Chem. 2007, 891-897.

  • An Efficient Preparation of New Sulfonyl Fluorides and Lithium Sulfonates. Toulgoat, F. ; Medebielle, M. ; Langlois, B.R. ; Sanchez, J.Y. J. Org. Chem. 2007, 72, 9046-9052.

  • Nucleophilic Trifluoromethylation of Aryl Halides with Methyl Trifluoroacetate. Langlois, B.R. ; Roques, N. J. Fluorine Chem. 2007, 128, 1318-1325.

  • A New Preparation of Trifluoromethanesulfinate Salts. Langlois, B.R. ; Billard, T. ; Mulatier, J.C. ; Yezeguelian, C. J. Fluorine Chem. 2007, 128, 851-856.

  • Electrochemical Investigation of Polymer Electrolytes Based on Aryl Perfluorosulfonate Lithium Salts. Paillard, E. ; Toulgoat, F. ; Sanchez, J.Y. ; Medebielle, M. ; Iojoiu, C. ; Alloin, F. ; Langlois, B. Electrochimica Acta 2007, 53, 1439-1443.

  • Selective aerobic oxidation of allylic alcohols to carbonyl compounds using catalytic Pd(OAc)2: High intramolecular selectivity Batt, F.; Bourcet, E.; Kassab, Y.; Fache, F. Synlett 2007, 1869-1872.

  • Tandem Sequential Ring-Closing Metathesis / Diels-Alder / Cross-Metathesis: Formation of Polycyclic Compounds by a New Three Component Reaction Virolleaud, M.A.; Piva, O. Eur. J. Org. Chem. 2007, 1606-1612.

  • Sequential cross-metathesis/cyclopropanation: short syntheses of (+/-)-cascarillic acid and (+/-)-grenadamide Salim, H.; Piva, O. Tetrahedron Lett. 2007, 48, 2059-2062.

  • Selective formation of dihydropyran derivatives by a tandem domino ring-closing metathesis/cross-metathesis. Virolleaud, M. A.; Piva, O. Tetrahedron Lett. 2007, 48, 1417-1420.

  • 2-(Prenyloxy)benzoyl (POMB): a New Temporary Protecting Group Removable by Intramolecular Cyclization. Vatèle, J.-M. Tetrahedron 2007, 63, 10921-10929.

  • A Route to the Tetrahydrofuran Segment of the Amphidinolides X and Y and its Quaternary-Carbon Epimer Doan, H.D.; Gallon, J.; Piou, A.; Vatèle, J.-M. Synlett 2007, 983-985.

  • Use of the olefin metathesis reaction for highly efficient β-cyclodextrin modification. Ghera, B.; Fache, F.; Parrot-Lopez, H. Tetrahedron 2006, 62, 4807-4813.

  • Functional anatomy of the therapeutic effects of prism adaptation on left neglect. Luaute, J. ; Michel, C. ; Rode, G. ; Pisella, L. ; Jacquin-Courtois, S. ; Costes, N. ; Cotton, F. ; Le Bars, D. ; Boisson, D. ; Halligan, P. ; Rosseti, Y. Neurology 2006, 66, 1859-1867.

  • Alveolar recruitment assessed by positron emission tomography during experimental acute lung injury Richard, J.C. ; Le Bars, D. ; Costes, N. ; Bregeon, F. ; Tourvieille, C. ; Lavenne, F. ; Janier, M. ; Gimenez, G. ; Guerin, C. Intensive Care Med. 2006, 32, 1889-1894.

  • Les molécules marquées au fluor-18: syntheses et application en imagerie médicale. Dolle, F. ; Perrio, C. ; Barre, L. ; Lasne, M.C. ; Le Bars, D. L’actualité Chimique 2006, 301-302.

  • Fluorine-18 and medical imaging : Radiopharmaceuticals for positron emission tomography. Le Bars, D. J. Fluor. Chem. 2006, 127, 1488-1489.

  • Simple synthesis of [11C]acetate. Le Bars, D. ; Malleval, M. ; Bonnefoi, F. ; Tourvieille C. J. Lab. Comp. Radiopharm. 2006, 49, 263-267

  • Reduced serotonin release in human sleep: evidence from an 18F-MPPF PET study. Derry, C. ; Bladin, P. ; Le Bars, D. ; Tochon-Danguy, H. ; Berkovic, S. ; Zimmer, L. ; Costes, N. ; Mulligan, R. ; Benjamin, C. ; Reutens, D. NeuroImage 2006, 30, 341-348.

  • Tendances et défis en chimie organique du fluor. Langlois, B. ; Ratton, S. ; Paris, J.M. L’Actualité Chimique, Octobre-Novembre 2006 (n° 301-302), pp. 56-66. (numéro spécial commémorant le 100e anniversaire de l’attribution du Prix Nobel à Henri Moissan)

  • Synthetic Applications of -Fluoroalkylated ,-Unsaturated Carbonyl Compounds. Billard, T. Chem. Eur. J. 2006, 12, 974-979.

  • Synthetic Applications of β-Fluoroalkylated Enones. 2. Use as Dienophiles in Diels-Alder Cycloadditions. Leuger, J.; Blond, G. ; Billard, T. ; Haufe, G. ; Langlois, B.R. J. Org. Chem. 2006, 71, 2735-2739.

  • Total and formal enantioselective synthesis of lyngbic acid and hermitamides A and B Virolleaud, M. A.; Menant, C.; Fenet, B.; Piva, O. Tetrahedron Lett. 2006, 47, 5127-5130.

  • Diastereoselective transannular [2+2] photocycloaddition of ascorbic acid derivatives Redon, S.; Piva, O. Tetrahedron Lett. 2006, 47, 733-736.

  • Yb(OTf)3-Catalyzed Oxidation of Alcohols with Iodosylbenzene Mediated by TEMPO. Vatèle, J.-M. Synlett 2006, 2055-2058.

  • One-pot Selective Oxidation/Olefination of Primary Alcohols using TEMPO-BAIB System and Stabilized Phosphorus Ylides. Vatèle, J.-M. Tetrahedron lett. 2006, 47, 715-718.

  • Double dissociation in neural correlates of visual working memory: A PET study Ventre-Dominey, J. ; Bailly, A. ; Lavenne, F. ; Le Bars, D. ; Mollion, H. ; Costes, N. ; Dominey, P. Brain Res. Cogn. Brain. Res. 2005, 25, 747-759.

  • [11C]-Methionine PET: dysembryoplastic neuroepithelial tumours compared with other epileptogenic brain neoplasms. Rosenberg, D. ; Demarquay, G. ; Jouvet, A. ; Le Bars, D. ; Streichenberger, N. ; Sindou, M. ; Kopp, N. ; Mauguiere, F. ; Ryvlin, P. J. Neurol. Neurosurg. Psychiatry. 2005, 76, 1686-1692.

  • A [18F]MPPF PET Normative Database of 5HT 1A Receptor Binding in Men and Women Over Age. Costes, N. ; Merlet, I. ; Ostrowsky, K. ; Faillenot, I. ; Lavenne, F. ; Zimmer, L. ; Ryvlin, P. ; Le Bars, D. J. Nucl. Med. 2005, 46, 1980-1989.

  • Quantitative assessment of regional alveolar ventilation and gas volume using 13N-N2 washout and PET. Richard, J.C. ; Janier, M. ; Lavenne, F. ; Tourvieille, C. ; Le Bars, D. ; Costes, N. ; Guerin, C. J. Nucl. Med. 2005, 46, 1375-83.

  • Tomographie par Emission de Positons: les possibilités de marquage au Fluor 18 Le Bars, D. Médecine Nucléaire 2005, 29, 190-195.

  • Brain processing of visual sexual stimuli in treated and untreated hypogonadal patients. Redoute, J. ; Stoleru, S. ; Pugeat, M. ; Costes, N. ; Lavenne, F. ; Le Bars, D. ; Dechaud, H. ; Cinotti, L. ; Pujol, J.F. Psychoneuroendocrinology 2005, 30, 461-82.

  • Towards the Syntheses of α-Trifluoromethylated Oxygenated Heterocycles and their Precursors. Hartong, S. ; Billard, T. ; Langlois, B.R. Synthesis 2005, 2253-2263.

  • A Concise Synthesis of Trifluoromethylated Cyclohexenones : a One-Pot-5 Step Domino Reaction. Christophe, C. ; Billard, T. ; Langlois, B.R. Eur. J. Org. Chem. 2005, 3745-3748.

  • Synthesis of α-Trifluoromethylated Nitrogen Bicycles. Ferry, A. ; Billard, T. ; Langlois, B.R. Synlett 2005, 1027-1029.

  • Electrophilic Aromatic Fluorination with Fluorine : Meta-Directed Fluorination of Anilines. Alric, J.P. ; Marquet, B. ; Billard, T. ; Langlois, B.R. J. Fluorine Chem. 2005, 126, 661-667.

  • Nucleophilic Trifluorometylation. Some Recent Reagents and their Stereoselective Aspects. Langlois, B.R. ; Billard, T. ; Roussel, S.J. Fluorine Chem. 2005, 126, 173-179.

  • From Fluoral to Heterocycles : A Survey of Polyfluorinated Iminium Chemistry Billard, T. ; Gille, S. ; Ferry, A. ; Barthelemy, A. ; Christophe, C. ; Langlois, B.R. J. Fluorine Chem. 2005, 126, 189-196.

  • Towards Enantioselective Nucleophilic Trifluoromethylation Roussel, S. ; Billard, T. ; Langlois, B.R. ; Saint-Jalmes, L. Chem. Eur. J. 2005, 11, 939-944.

  • Synthesis of (R)-Arundic Acid Pelotier, B.; Holmes, T.; Piva, O. Tetrahedron: Asymmetry 2005, 16, 1513-1520.

  • Synthesis of Polycyclic Lactams and Sultams by a Cascade Ring-Closure Metathesis /Isomerization and Subsequent Radical Cyclization Bressy, C.; Menant, C.; Piva, O. Synlett 2005, 577-582.

  • Total synthesis of cimiracemate B and analogs Fache, F.; Suzan, N.; Piva, O. Tetrahedron 2005, 61, 5261-5266.

  • 2-(Prenyloxy)benzoyl (POMB) as a New Temporary Protecting Group for Alcohols Vatèle, J.-M. Tetrahedron Lett. 2005, 46, 2299-2301.